Grade 10 → Thermal physics → Laws of Thermodynamics ↓
Zeroth law of thermodynamics
The zeroth law of thermodynamics is a fundamental principle that plays a vital role in understanding how thermal equilibrium works. It may seem complicated, but it's quite simple once you understand it.
Understanding thermal equilibrium
Imagine you have a cup of hot coffee and a metal spoon. If you put the spoon in the coffee, what happens after a while? The spoon gets hotter. Why does this happen? This is due to the principle of reaching thermal equilibrium. In simple terms, objects in contact exchange heat until they reach the same temperature.
Now, let's think of a third object, say another spoon which is initially at room temperature. If we simply put this new spoon in contact with the first spoon (which is already hot), the two spoons will eventually reach the same temperature due to heat transfer. If these spoons are placed in two different cups of water and the heat level in the water becomes the same, this will clearly reveal the equality of temperature between these three different objects, without putting them in contact together.
Zeroth law explained
The zeroth law of thermodynamics states: if two systems are in thermal equilibrium with a third system, then they will also be in thermal equilibrium with each other.
a = c b = c => a = b
Here, A, B, and C are systems. If A is in thermal equilibrium with C, and B is also in thermal equilibrium with C, then A and B must be in thermal equilibrium with each other.
Visual example
Let us understand this principle in a little more detail:
Here, systems A and B are not in direct contact, but both are in contact with system C. The zeroth law shows that if A and C are in equilibrium and similarly for B and C, then A and B will be in equilibrium indirectly.
Importance of zeroth law
The zeroth law is very important because it allows us to define the concept of temperature. Without this law, the idea of temperature would be meaningless because there would be no way to measure or compare the thermal states of different systems.
Consider thermometers: they work on the principle of the zeroth law. When you use a thermometer to take your body temperature or check the temperature of a liquid, what you are doing is putting the thermometer in thermal equilibrium with the system. The reading stabilizes when both the thermometer and the system reach the same temperature, allowing you to make meaningful temperature comparisons.
Practical example
To make the zeroth law relevant, think of these everyday examples:
- Calibration of instruments: Temperature-measuring devices, such as ovens and refrigerators, rely on the zeroth law to ensure that their readings reflect the actual temperatures inside them.
- Weather thermometer: Outdoor thermometers must reach thermal equilibrium with the surrounding air to provide accurate temperature readings.
- Cooking: When you set a temperature on an oven, the oven needs to reach thermal equilibrium at that temperature before cooking begins. This ensures that the food is cooked properly.
Relation to other laws of thermodynamics
The zeroth law lays the foundation for all the other laws of thermodynamics by establishing the concept of temperature. Other laws, such as the first law of thermodynamics, which deals with energy conservation (often written as ΔU = Q - W
), require a clear understanding of temperature and heat flow.
Conclusion
Understanding the zeroth law of thermodynamics helps us understand how temperature measurements work and how heat attempts to achieve equilibrium between systems. It teaches us that discussing equilibrium does not require physical contact between all objects, thanks to the bridging role of a third system. Remember, the primary contribution of the zeroth law is that it defines temperature as a fundamental and intuitive concept.