Undergraduate → Nuclear and particle physics → Atomic Structure ↓
Atomic Model
Atomic models are conceptual frameworks used to understand the structure and behaviour of the atomic nucleus. These models play an important role in atomic physics and help explain various experimental observations. Understanding the structure of the nucleus is essential for understanding the fundamental nature of matter as well as for applications in energy production, medicine, and even archaeology.
Fluid droplet model
The fluid drop model treats the nucleus as if it were a drop of incompressible fluid. This analogy helps explain certain nuclear properties such as binding energy, fission, and fusion. This model is based on several assumptions that simplify the complex nature of nuclear forces.
The model includes several components. The binding energy of the nucleus ( E_b ) can be expressed using the semi-empirical mass formula:
E_b = a_v A - a_s A^{2/3} - a_c frac{Z^2}{A^{1/3}} - a_a frac{(NZ)^2}{A} + delta(A,Z)
Where:
- ( A ) is the mass number (total number of protons and neutrons)
- ( Z ) is the atomic number (number of protons)
- ( N ) is the neutron number
- ( a_v ), ( a_s ), ( a_c ), and ( a_a ) are constants representing the volume, surface, Coulombic, and asymmetry energy terms, respectively
- ( delta(A,Z) ) is the pairing term, which describes the effects of atomic pairing
The liquid drop model uses these terms to model the overall size and stability of the nucleus. For example, the volume term ( a_v A ) represents the nuclear force binding energy that is proportional to the number of nucleons, similar to that of molecules bound in a liquid. The surface term ( -a_s A^{2/3} ) represents the reduction in binding energy due to fewer neighbors of the nucleon on the surface of the nucleus.
Liquid drop model use example
Consider uranium-238 (U-238). Using the semi-empirical mass formula, we can calculate the predicted binding energy and compare it to actual experimental values to validate the effectiveness of the model.
Shell model
The shell model describes the nucleus using the concept of individual nucleons (protons and neutrons), which move in discrete energy levels, similar to electrons in an atom. The model is particularly successful in explaining magic numbers in the nucleus - the number of protons or neutrons at which a nucleus is particularly stable.
In the shell model, nucleons move in a potential well created by the average forces from other nucleons. This potential is often modeled as a harmonic oscillator or Woods-Saxon potential. Energy levels for nucleons in this potential are quantized.
H psi = E psi
Where:
- ( H ) is the Hamiltonian operator representing the total energy
- ( psi ) is the wave function of the nucleon
- ( E ) is the energy eigenvalue
Magic numbers
In the shell model, magic numbers arise at certain nucleon numbers where there are large energy gaps between filled and empty energy levels. These are similar to the noble gases present in atomic shells.
- Magic numbers for protons and neutrons include 2, 8, 20, 28, 50, 82, and 126.
Collective models
The collective model is a hybrid of the liquid drop and shell models, providing a more comprehensive view of the atomic structure. It considers the collective motion of nucleons and is particularly useful for explaining atomic deformations and excited states.
This model incorporates rotation and vibration modes of the nucleus, which are similar to the oscillations that occur in a macroscopic object.
Deformation and rotation
Nuclei can deform from a spherical shape and rotate. This deformation is represented mathematically as follows:
beta = frac{Q_0}{Z R_0^2}
Where:
- ( beta ) is the distortion parameter
- ( Q_0 ) is the electric quadrupole moment
- ( R_0 ) is the nuclear radius
Rotational motion is often described using energy levels that depend on the angular momentum (J):
E(J) = frac{hbar^2}{2mathcal{I}} J(J+1)
Where:
- ( hbar ) is the reduced Planck constant
- ( mathcal{I} ) is the moment of inertia of the nucleus
Nuclear forces
At the core of all these models are the nuclear forces, which are responsible for binding the nucleons together. The strong nuclear force is much stronger than the electromagnetic force, but has a shorter range.
The residual strong force, which holds the nuclei together, can be described qualitatively by the Yukawa potential:
V(r) = -g^2 frac{e^{-mu r}}{r}
Where:
- ( g ) is the coupling constant
- ( mu ) is related to the mass of the meson that mediates the force
- ( r ) is the distance between nucleons
Conclusion
The study of atomic models provides important information about the properties and behaviour of the atomic nucleus. Although none of these models by itself gives a complete picture, together they provide a comprehensive understanding of the atomic structure. Atomic models such as the liquid droplet model, the shell model and the collective model take into account various aspects of the nucleus and are confirmed by experimental data, contributing to our understanding of the fundamental nature of matter.